ASTM A194 Grade 9CA specifies premium super-austenitic stainless steel nuts, widely recognized in the industry under the UNS N08367 designation (often referred to commercially as AL-6XN®). This ultra-high-performance alloy is heavily enriched with Chromium (20-22%), Nickel (23.5-25.5%), and Molybdenum (6-7%), while maintaining a strictly controlled low-carbon profile. This elite chemistry imparts extraordinary resistance to chloride-induced pitting, crevice corrosion, and stress corrosion cracking (SCC), making it a superior alternative to standard 300-series alloys in aggressive environments.
What distinguishes Grade 9CA is the critical "A" designation, which mandates that the fasteners undergo a final Carbide Solution Treatment (full annealing) after all forging, machining, and thread-tapping operations are completed. This vital thermal process eliminates any residual cold-work stresses, ensuring a fully softened, strictly non-magnetic state (60-90 HRB). This structural restoration maximizes the alloy's resistance to Stress Corrosion Cracking in highly aggressive chemical and marine applications.
| Material Classification | Super Austenitic Stainless Steel (6% Moly Grade - Annealed) |
|---|---|
| UNS Designation | N08367 |
| Microstructure | Fully Austenitic (Post-Annealed) |
| Magnetic State | Strictly Non-Magnetic (Annealed post-machining) |
| Density | ~8.06 g/cm³ (0.291 lb/in³) |
| Size Range | Metric: M6 to M100 | Imperial: 1/4" to 4" |
| Strengthening Method | Full Solution Annealing After Machining |
Contains detailed proof load thresholds, dimensional tolerances for ASME B18.2.2 standard and heavy hex profiles, and critical high-temperature torque values.
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| Carbon (C) | Manganese (Mn) | Phosphorus (P) | Sulfur (S) | Silicon (Si) | Chromium (Cr) | Molybdenum (Mo) | Nickel (Ni) |
|---|---|---|---|---|---|---|---|
| 0.030 Max | 2.00 Max | 0.040 Max | 0.030 Max | 1.00 Max | 20.0 – 22.0 | 6.0 – 7.0 | 23.5 – 25.5 |
Because Grade 9CA is explicitly annealed after all machining to remove localized cold-work hardening, ASTM tightly controls the hardness range to guarantee the matrix remains fully softened and stress-free.
| Mechanical Property | Grade 9CA (Annealed) Limits |
|---|---|
| Hardness Limit (Rockwell) | 60 - 90 HRB Maximum |
| Proof Load | Dependent on Size |
| Standard / System | Designation |
|---|---|
| ASME Standard | SA194 Grade 9CA |
| Common Trade Name | AL-6XN® (Annealed), 6% Moly Nuts, UNS N08367 |
| European Equivalent | EN 1.4529 / X1NiCrMoCuN25-20-7 (Approximate) |
| Internal Threads (A194 Gr 9CA) | Mating Bolts (Equivalent Alloy) | Mating Studs (Equivalent Alloy) |
|---|---|---|
| Grade 9CA Heavy Hex Nuts | UNS N08367 Heavy Hex Bolts | UNS N08367 Fully Threaded Studs |
Due to the incredibly high alloy content and the fully austenitic nature of 9CA, thread galling is a significant risk under high clamping loads. Premium, heavy-duty anti-seize lubrication (such as nickel or molybdenum-disulfide based pastes) is absolutely mandatory for installation.
| Nominal Diameter | Threads Per Inch (UNC) | Target Torque — Lubricated (ft-lbs) |
|---|---|---|
| 1/2" | 13 | 45 |
| 5/8" | 11 | 90 |
| 3/4" | 10 | 150 |
| 1" | 8 | 350 |
The "A" indicates that the component has been Annealed after all manufacturing and machining processes are complete. This removes all internal cold-work stresses generated during machining, ensuring the part is fully softened and strictly non-magnetic to maximize resistance against Stress Corrosion Cracking.
Because the "A" specification is designed to eliminate stress through annealing, the hardness is restricted between 60 and 90 HRB. If a nut measures harder than this, it indicates residual cold-work stress remains from the manufacturing process, and it would fail the 9CA specification.
No, it is a fully Super Austenitic stainless steel alloy. While its corrosion resistance is often compared to Super Duplex grades, its high Nickel (23.5-25.5%) fully austenitic microstructure gives it superior ductility and toughness across extreme temperature ranges.