Titanium Grade 4 (UNS R50700) is the absolute strongest classification of Commercially Pure (CP) Titanium. It serves as the ultimate bridge between the severe formability of the lower CP grades and the immense strength of alloyed titanium (like Grade 5). This exceptional strength is achieved by intentionally maximizing the allowable interstitial Oxygen and Iron content, which stiffens the alpha-phase crystal structure to yield mechanical properties that rival mild steel.
Because it contains no Aluminum or Vanadium, Grade 4 retains the phenomenal, uncompromised corrosion resistance of pure titanium. It is totally immune to chloride stress-corrosion cracking, pitting in marine environments, and degradation in oxidizing acids. UNS R50700 fasteners are the mandatory choice for applications demanding the absolute highest structural yield possible without sacrificing the biocompatibility or chemical inertness of unalloyed titanium, making them essential in aerospace airframes, severe chemical processing, and critical load-bearing medical implants.
| Material Classification | Commercially Pure (CP) Titanium - Highest Strength Grade |
|---|---|
| UNS Designation | R50700 |
| Microstructure | Single-Phase Alpha Matrix |
| Magnetic State | Completely Non-Magnetic |
| Density | 4.51 g/cm³ (0.163 lb/in³) — Exceptionally Lightweight |
| Size Range | Metric: M4 to M36 | Imperial: #8 to 1-1/2" |
| Primary Attribute | Maximum Yield Strength of all Unalloyed Titanium Grades |
Contains detailed high-load structural shear thresholds, dynamic fatigue limits for aerospace applications, and specialized machining parameters for hard CP titanium.
⬇ DOWNLOAD DATASHEETIn high-stress aerospace and biomedical applications, the precise management of Oxygen and Iron dictates the metal's performance limit. Exceeding the maximum allowed limits causes catastrophic embrittlement. Ananka ensures every Grade 4 fastener lot is backed by rigorous, aerospace-grade Vacuum Arc Remelting (VAR) certification.
Grade 4 represents the physical limit of strengthening unalloyed titanium via interstitial elements. It allows the highest concentration of Oxygen (up to 0.40%) and Iron (up to 0.50%) of any CP grade. This deliberate inclusion creates a highly rigid, strong alpha-phase matrix without resorting to heavy alloying elements like Aluminum or Vanadium.
| Titanium (Ti) | Oxygen (O) | Iron (Fe) | Carbon (C) | Nitrogen (N) | Hydrogen (H) |
|---|---|---|---|---|---|
| Balance (~98.9) | 0.40 Max | 0.50 Max | 0.08 Max | 0.05 Max | 0.015 Max |
| Mechanical Property | Typical Limits (Annealed Temper) |
|---|---|
| Tensile Strength | 80,000 psi (550 MPa) Minimum |
| Yield Strength (0.2% Offset) | 70,000 - 85,000 psi (480 - 585 MPa) |
| Elongation (in 2 inches) | 15% Minimum |
| Hardness (Brinell) | ~ 230 HB (approx. 98 HRB) |
| Standard / System | Designation |
|---|---|
| ASTM Specifications | ASTM B348 (Rod/Bar), ASTM F467 / F468 (Fasteners) |
| Common Trade Names | CP Titanium Grade 4, Unalloyed Titanium |
| Medical Specifications | ASTM F67 (Unalloyed Titanium for Surgical Implant) |
| European Equivalent | EN 3.7065 (Ti4) |
| Mating Bolts/Studs | Internal Threads (Nuts) | Washers / Gaskets |
|---|---|---|
| Grade 4 CP Titanium Heavy Hex Bolts | Grade 4 CP Titanium Hex Nuts | Grade 4 Flat Washers / PTFE |
Due to its high structural rigidity, Grade 4 Titanium can withstand aggressive torque loads comparable to many carbon steels. However, because it remains an unalloyed titanium, the risk of severe thread galling (cold-welding) is extremely high under heavy friction. Generous application of premium dialectric anti-seize pastes or specialized Teflon dry-films is absolutely mandatory before applying torque.
| Nominal Diameter | Threads Per Inch (UNC) | Max Target Torque (in-lbs) — Lubricated | Max Target Torque (ft-lbs) — Lubricated |
|---|---|---|---|
| 1/4" | 20 | 65 - 75 | ~ 5.5 |
| 5/16" | 18 | 140 - 160 | ~ 12.5 |
| 3/8" | 16 | 250 - 280 | ~ 22.0 |
| 1/2" | 13 | 520 - 580 | ~ 46.0 |
It comes down to a balance of strength, ductility, and absolute corrosion resistance. Grade 5 is significantly stronger due to Aluminum and Vanadium, but those alloys reduce its ductility (making it more brittle) and slightly decrease its corrosion resistance in certain highly specific, extreme chemical environments. Grade 4 offers the absolute highest strength possible while remaining 100% commercially pure, making it tougher and more chemically inert than Grade 5.
Generally, no. The high oxygen and iron content that gives Grade 4 its strength also makes it quite rigid and difficult to form at room temperature. If you attempt to aggressively cold-head Grade 4 wire into a bolt head, the metal is highly likely to crack. Fasteners made from Grade 4 are predominantly manufactured via CNC machining from solid bar stock or through hot-forging processes.
Yes, absolutely. Grade 4 is fully recognized by ASTM F67 as an approved material for surgical implants. Because it contains no Vanadium (which is mildly toxic and present in Grade 5), it is heavily favored for high-load orthopedic implants, such as hip joint replacements and spinal rods, where both extreme strength and perfect biocompatibility are required.