ASTM A194 Grade 16 specifies high-strength, quenched and tempered chromium-molybdenum-vanadium (Cr-Mo-V) alloy steel nuts engineered explicitly for extreme high-temperature and high-pressure service environments. While utilizing a robust alloy foundation similar to Grade 4 and Grade 7, the strategic addition of vanadium fundamentally alters the material's microstructural high-heat stability.
This precisely alloyed material is designed to prevent structural relaxation and creep deformation under sustained massive clamping loads at temperatures well beyond the safe operating limits of standard carbon and low-alloy steels. Grade 16 nuts are the premier, uncompromising fastening solution for superheated steam piping, power generation turbines, and advanced high-temperature petrochemical processing.
ASTM A194 Grade 16 represents the absolute peak of non-stainless alloy performance for high-temperature pressure piping components.
| Material Classification | Quenched & Tempered Cr-Mo-V Alloy Steel Heavy Hex Nuts |
|---|---|
| UNS Designation | K14072 |
| Microstructure | Tempered Martensite |
| Magnetic State | Magnetic |
| Density | ~7.85 g/cm³ (0.284 lb/in³) |
| Size Range | Metric: M6 to M100 | Imperial: 1/4" to 4" Custom oversized nuts available upon request. |
| Thread Types | UNC, UNF, 8UN, Metric Coarse, Metric Fine |
| Strengthening Method | Quenching & High-Temperature Tempering (Min 1200°F / 650°C) |
Access professional-grade technical data for ASTM A194 Grade 16, including extreme-temperature creep thresholds, high-heat dimensional stability metrics, and mating bolt torque charts.
Contains detailed proof load thresholds up to 175 ksi, dimensional tolerances for ASME B18.2.2 heavy hex profiles, and specific dry and lubricated installation torque values for high-temperature B16 assemblies.
⬇ DOWNLOAD DATASHEETMaterial traceability is the backbone of safety in extreme-service thermal systems. Every lot shipped by Ananka is accompanied by fully authenticated documentation mapping back to raw steel mill certificates.
Grade 16 incorporates Vanadium (V) alongside Chromium (Cr) and Molybdenum (Mo). This highly controlled combination pins the grain boundaries and creates extremely stable carbides, severely restricting thermal expansion and preventing high-temperature creep.
| C | Mn | Cr | Mo | V | Si | P (Max) | S (Max) | Al (Max) |
|---|---|---|---|---|---|---|---|---|
| 0.36–0.47 | 0.45–0.70 | 0.80–1.15 | 0.50–0.65 | 0.25–0.35 | 0.15–0.35 | 0.035 | 0.040 | 0.015 |
Grade 16 is tested to demanding proof load stress limits at room temperature, ensuring it has the foundational strength required before being subjected to punishing thermal loads.
| Mechanical Property | Up to 1-1/2" Diameter | Over 1-1/2" Diameter |
|---|---|---|
| Proof Load Stress (Heavy Hex) | 175 ksi (1205 MPa) | 150 ksi (1034 MPa) |
| Proof Load Stress (Standard Hex) | 150 ksi (1034 MPa) | 120 ksi (827 MPa) |
| Hardness Range (Rockwell C) | 24 to 35 HRC | 24 to 35 HRC |
| Hardness Range (Brinell) | 248 to 327 HBW | 248 to 327 HBW |
| Standard / System | Designation |
|---|---|
| ASME Standard | SA194 Grade 16 |
| Common Trade Name | A194 Gr. 16 Cr-Mo-V Nuts |
| European Equivalent | EN 1.7711 / 40CrMoV4-6 (Approximate Match) |
Grade 16 nuts are specified for the absolute most demanding, non-corrosive high-heat environments where standard alloy steels would rapidly fail.
To ensure uniform thermal expansion, matched creep resistance, and to prevent galvanic-induced failure, Grade 16 nuts must be paired exclusively with matching Cr-Mo-V bolting.
| Nuts (A194 Gr 16) | Mating High-Temp Bolts | Mating High-Temp Studs |
|---|---|---|
| Heavy Hex Nuts | ASTM A193 Grade B16 Heavy Hex Bolts | ASTM A193 Grade B16 Fully Threaded Studs |
| Standard Hex / Jam Nuts | ASTM A193 Grade B16 Socket Head Screws | ASTM A193 Grade B16 Double End Studs |
Manufactured to meet the most stringent international dimensional and material codes.
The following torque values are approximate for A193 B16 studs mated with A194 Grade 16 heavy hex nuts. High-temperature anti-seize lubrication (often nickel, copper, or graphite-based) is vital to prevent severe thread galling at extreme temperatures.
| Nominal Diameter | Threads Per Inch (UNC) | Target Torque — Dry (ft-lbs) | Target Torque — Lubricated (ft-lbs) |
|---|---|---|---|
| 1/2" | 13 | 90 | 65 |
| 5/8" | 11 | 180 | 130 |
| 3/4" | 10 | 320 | 230 |
| 1" | 8 | 770 | 550 |
Ananka Group is a leading manufacturing-driven organization specializing in high-performance, thermally stable bolting packages for the global energy and infrastructure sectors.
While Grades 4 and 7 utilize Carbon-Molybdenum and Chromium-Molybdenum respectively, Grade 16 is alloyed with Vanadium (Cr-Mo-V). This specific addition creates highly stable carbides that dramatically improve the material's resistance to high-temperature creep and structural relaxation, outperforming both Grade 4 and 7 in extreme heat.
To ensure identical thermal expansion rates and consistent high-temperature capabilities across the joint, ASTM A194 Grade 16 nuts must be mated exclusively with ASTM A193 Grade B16 studs and bolts.
Due to the robust Cr-Mo-V alloy matrix, Grade 16 nuts can reliably perform in environments reaching up to approximately 1100°F (593°C), making them a staple in power generation and superheated steam lines.
Genuine Grade 16 nuts are stamped on the bearing face or side with the manufacturer's identification mark alongside the number "16" to explicitly denote the ASTM grade.
For project-specific technical support or to request a quote for ASTM A194 Grade 16 fasteners, please contact the Ananka Group Sales and Engineering Team at sales@anankafasteners.com or via WhatsApp at +91 86557 47687. Secure your critical infrastructure with certified components and world-class manufacturing expertise.